Taipei Medical University

A B C D E F G H I J K L M N O P Q R S T U V W X Y Z
Liou JP
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------>journal_name=11/655088
------>paper_name=Z-stilbenes ?????????
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------>fullAbstract=[reaction: see text] Diastereodifferentiating [2+2] photocycloadditions of (E)- and (Z)-stilbenes to bis((R)-1-methylpropyl) fumarate were performed through the direct excitation of stilbenes and the selective excitation of the charge-transfer (CT) complex at various temperatures. The geometrical isomers of stilbene afforded the opposite diastereomers of mu-truxinate in both excitation modes, with a dramatic decrease in the product~s diastereoselectivity upon prolonged irradiations.
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------>authors2=Chang JY
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------>authors=Liou JP
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------>updateTitle=Switching of product~s chirality in diastereodifferentiating [2+2] photocycloaddition of (E)- versus (Z)-stilbene to chiral fumarate upon direct and charge-transfer-band excitation.
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------>patent_SDate=2007-01-19 00:00:00
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------>publish_year=2009
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A B C D E F G H I J K L M N O P Q R S T U V W X Y Z